 oxidation catalyst, process for manufacturing the oxidation catalyst, method for treating exhaust ga
专利摘要:
OXIDATION CATALYST, OXIDATION MANUFACTURING PROCESS, METHOD FOR TREATING EXHAUST GAS EMISSIONS FROM INTERNAL COMBUSTION ENGINES, EXHAUST SYSTEM FOR AN INTERNAL COMBUSTION ENGINE, AND, VEHICLE An oxidation catalyst comprises an extruded solid body comprising: 10- 100% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight of optionally stabilized ceria, such catalyst comprising at least one precious metal and optionally at least one precious metal and optionally at least one non-precious metal, wherein: (i) most of the at least one precious metal is located on a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface of the extruded solid body; (iii) at least one metal is present throughout the extruded solid body and is also present in a higher concentration on a surface of the extruded solid body; (iv) at least one metal is present throughout the extruded solid body and is also carried in one more coating layer(s) over a (...). 公开号:BR112012019030B1 申请号:R112012019030-0 申请日:2011-02-01 公开日:2021-05-25 发明作者:Paul Joseph Andersen；David Bergeal；Hsiao-Lan Chang；Hai-Ying Chen；Julian Peter Cox；Ralf Dotzel；Rainer Leppelt；Jörg Werner Münch；Hubert Schedel；Duncan John William Winterborn；Todd Howard Ballinger 申请人:Johnson Matthey Plc； IPC主号:
专利说明:
[0001] The present invention relates to an oxidation catalyst comprising an extruded solid body for use in the treatment of exhaust gas emissions from internal combustion engines from stationary and mobile sources, i.e., vehicular (automotive) applications. [0002] The Society of Automotive Engineers (SAE) technical publication 2007-01-0658 entitled "Fundamental Study and Possible Application of New Concept Honeycomb Substrate for Emission Control" discloses a diesel oxidation catalyst (DOC) comprising a catalyst for platinum dispersed on a catalytic support comprising a plurality of extruded segments of gamma-alumina, inorganic fibers and binder material (not named) adhesively combined into a full-sized block. Platinum is applied to the catalytic support by a standard impregnation method at 1.0 to 2.7 g per liter. [0003] Patent document EP 1739066 discloses a honeycomb structure comprising multiple honeycomb structures having multiple through holes; and a sealing layer joining the honeycomb units together via the respective closed outer faces of the honeycomb units where the through holes are not open. The honeycomb unit includes at least inorganic particles, bristles and/or inorganic fibers. The exemplified inorganic particles are alumina, titania, silica and zirconia; the exemplified inorganic fibers are silica-alumina fibers; and the exemplified inorganic binders are silica sol, sepiolite and attapulgite. A catalytic component may be carried over the honeycomb structure. The catalyst component may include at least one type selected from noble metals including platinum, palladium and rhodium, alkali metals such as potassium and sodium, alkaline earth metal e.g. barium and oxides. The honeycomb structure can be used as a catalytic converter e.g. a three-way catalyst or a NOx storage catalyst for conversion of vehicle exhaust gas. [0004] It has now been developed an oxidation catalyst comprising an extruded solid body and at least one metal with special application in the field of exhaust gas after treatment of exhaust gas from internal combustion engine. Such exhaust gases can result from stationary source emissions, but have been developed for use in particular for treating mobile sources of emissions such as passenger cars, trucks and buses. [0005] According to one aspect, the invention provides an oxidation catalyst comprising an extruded solid body comprising: 10-100% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight of optionally stabilized ceria, such catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) most of the at least one precious metal is located on a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface of the extruded solid body; (iii) at least one metal is present throughout the extruded solid body and is also present in a higher concentration on a surface of the extruded solid body; (iv) at least one metal is present throughout the extruded solid body and is also carried in one or more coating layer(s) on a surface of the extruded solid body; or (v) at least one metal is present throughout the extruded solid body, is present in a greater concentration on a surface of the extruded solid body, and is also carried in one or more layer(s) on the surface of the extruded solid body. [0006] An advantage of the present invention is that by removing the catalytic components that are often used in catalytic coatings, the number of coatings can be reduced, e.g. from two layers to one layer; or a single layer can be removed entirely and the catalytic metal can be carried over a surface of the solid body extruded as such. This has benefits in reducing back pressure in an exhaust system, increasing engine efficiency. [0007] Furthermore, by providing the possibility of uncoated catalysts, the extruded solid body can be manufactured in higher cell density, increasing strength and decreasing cell wall thickness which can improve ignition performance and increase activity through mass transference. [0008] It is also possible to increase the volume of active components in an extruded solid body relative to a coating on an inert monolithic substrate. This increased catalyst density has advantages for long-lasting durability and catalyst performance, which is important for on-board diagnostics. [0009] “On-board diagnostics” (OBD) in the context of a motor vehicle is a generic term to describe the self-diagnostic and reporting capability of vehicle systems provided by a network of sensors linked to a suitable electronic control system. Early examples of OBD systems simply illuminated a malfunction indicator light if a problem was detected, but provided no information about the nature of the problem. Most modern OBD systems use a standardized digital connection port and are able to provide information on standardized diagnostic trouble codes and a real-time data selection that allows for quick identification and troubleshooting of a vehicle's systems. [00010] Current OBD requirements require that a driver needs to be notified in the event of a malfunction or deterioration of the emission system that would cause emissions to exceed mandatory limits. So, for example, the OBD limits for Euro 4: 98/69/EC for diesel passenger vehicles (category M vehicles as defined by 70/156/EEC) are: carbon monoxide (CO) = 3.2g/ km; hydrocarbons (HC) = 0.4 g/km; nitrogen oxides (NOx) = 1.2 g/km; and particulate matter (PM) = 0.18 g/km. [00011] Future legislation on vehicular emissions, especially in the US and Europe, requires greater sensitivity in diagnostic function in order to continuously monitor the ability of an exhaust system post-treatment catalyst to comply with emission legislation. For example, current draft OBD limits for Euro 5: 715/2007/EC for compression ignition (diesel) passenger vehicles are: CO = 1.9 g/km; non-methane hydrocarbons (NMHC) = 0.25 g/km; NOx = 0.54 g/km; MW = 0.05 g/km. [00012] In the USA it is understood that the OBD II legislation ("Title 13, California Code Regulations, Section 1968.2, Malfunction and Diagnostic System Requirements for 2004 and Subsequent Model-Year Passenger Cars, Light-Duty Trucks and Medium-Duty Vehicles and Engines ”) to monitor spark ignited/gasoline engine catalytic converters requires a malfunction signal where the average Federal Test Procedure (FTP) test for NMHC conversion efficiency of a monitored portion of a catalytic system drops below 50%. [00013] Extruded solid bodies according to the present invention generally comprise a unitary honeycomb structure having parallel and uniformly sized channels extending from a first end to a second end thereof. Generally, channels are open at both the first and second ends - a so-called “straight-through” configuration. Channel walls defining the channels are porous. Typically an outer "skin" surrounds a plurality of channels of the extruded solid body. The extruded solid body can be formed of any desired cross section, such as circular, square or oval. Individual channels in the plurality of channels can be square, triangular, hexagonal, circular, etc. Channels at a first upstream end may be blocked e.g. with a suitable ceramic cement, and unblocked channels at the first upstream end may also be blocked at a second downstream end to form a so-called wall flow filter. Typically, the arrangement of blocked channels at the first upstream end resembles a chessboard with a regular arrangement of open and blocked downstream channel ends. [00014] It is clear that the honeycomb structure disclosed in EP 1739066 has a Thermal Shock Parameter (TSP) too low to be used in a single unitary extrudate, because the honeycomb structure comprises an assembly of units of individual honeycomb cemented together. This arrangement, also seen in the form of commercially available silicon carbide honeycombs, is designed to avoid catastrophic catalytic substrate failure due to inter alia thermal shock as a result of a relatively high Thermal Expansion Coefficient (CTE) of the material. extruded. However, manufacturing a honeycomb structure from individual honeycomb units is complicated, laborious, time-consuming and expensive and increases the number of possible physical failure modes, eg in cement connections, compared to a one-piece extrusion. A more complete explanation of TSP and CTE can be found in "Catalytic Air Pollution Control - Commercial Technology", Second Edition, RM Heck et al., John Wiley & Sons, Inc., New York, 2002 Chapter 7 (in relation to direct flow monoliths) and 9 (for wall flow filters). [00015] Consequently, it is preferred that the extruded solid body of the catalyst according to the invention has an axial Thermal Shock Parameter (TSP) and a radial TSP sufficient to prevent radial cracks and annular cracks in the extruded solid body when used to treat gases exhaust from a stationary or mobile source of emissions. In this way the extruded solid body can be formed from a single unitary extrudate. For extruded solid bodies having an especially large cross section, it may still be necessary to extrude segments of the extruded solid body for joint cementation. However, this is due to difficulties in processing extrudates of such a large cross section, or because of limitations on the size of the extrudate mold tool. Considered individually, however, each segment of the entire catalyst would meet the functional limitation that the axial TSP and radial TSP are sufficient to prevent radial cracks and annular cracks in the individual extruded solid body segments when used to treat exhaust gases from a stationary source or mobile emissions. In one modality the radial TSP is >0.4 to 750°C, such as >0.5, >0.6, >0.7, >0.8 >0.9 or >1.0. At 800°C the radial TSP is also desirably >0.4 and at 1000°C it is preferably >0.8. [00016] The CTE of wall flow filters is preferably 20 x 10-7/°C for the purpose of being formed from a one-piece extrudate. [00017] In embodiments, the at least one binder/matrix component can be selected from the group consisting of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, a spinel, an optionally doped alumina, a silica source, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more of these. [00018] Spinels can be MgAl2O4 or the Mg can be partially replaced by a metal from the group consisting of Co, Zr, Zn or Mn. The MgO content in MgAl2O4 relative to Al2O3 can be from 0.8 to 2.5, with values of <1.0 preferred. [00019] The alumina binder/matrix component is preferably gamma-alumina, but can be any other transition metal alumina, i.e. alpha-alumina, beta-alumina, chi-alumina, eta-alumina, rô-alumina, cap - alumina, theta-alumina, delta-alumina, lanthanum-beta-alumina and mixtures of any two or more such transitional aluminas. [00020] It is preferred that the alumina be doped with at least one non-aluminum element to increase the thermal stability of the alumina. Suitable alumina dopants include silicon, zirconium, barium, lanthanides and mixtures of any two or more of these. Suitable lanthanide dopants include La, Ce, Nd, Pr, Gd and mixtures of any two or more of these. [00021] Silica sources may include a silica, a silica sol, quartz, fused or amorphous silica, sodium silicate, an amorphous aluminosilicate, an alkoxysilane, a silicone resin binder such as methyl-phenyl-resin silicone, a clay, talc or a mixture of any two or more of these. [00022] From this list, the silica can be SiO2 such as, feldspar, mullite, silica-alumina, silica-magnesia, silica-zirconia, silica-toria, silica-berylia, silica-titania, ternary silica-alumina-zirconia, ternary silica-alumina-magnesia, silica-magnesia-zirconia ternary, silica-alumina-torium ternary and mixtures of any two or more of these. Alternatively, silica can be derived from calcining tetramethyl orthosilicate (TMOS) added to the extrusion composition. [00023] Suitable clays include fuller's chalk, sepiolite, hectorite, a smectite, a kaolin and mixtures of any two or more of these, the kaolin being chosen from subbentonite, anauxite, halloysite, kaolinite, dickite, nacrite and mixtures of any two or more of these; smectite may be selected from the group consisting of montmorillonite, nontronite, vermiculite, saponite and mixtures of any two or more of these; and fuller chalk may be montmorillonite or palygorskite (atapulgite). [00024] Inorganic fibers are selected from the group consisting of carbon fibers, glass fibers, metal fibers, boron fibers, alumina fibers, silica fibers, silica-alumina fibers, silicon carbide fibers, titanate fibers potassium, aluminum borate fibers and ceramic fibers. [00025] Molecular sieves suitable for use in the present invention are those capable of adsorbing unburned hydrocarbons after cold starting of an automobile engine and desorbing adsorbed hydrocarbons at room temperature, eg when an associated precious metal-based oxidation catalyst component has reached a desired ignition temperature for eg CO and HC oxidation or NOx reduction. Such molecular sieves are generally not those having an 8-ring open pore structure as their larger porous open structure, sometimes called "small pore" molecular sieves . Preferred molecular sieves are medium pore (maximum 10 ring open pore structure), large pore (maximum 12 ring open pore structure) or oven-meso-pore (>12 ring open pore structure) molecular sieves . [00026] The or each zeolitic molecular sieve or the or each non-zeolitic molecular sieve can be selected from a type of code frame ABW, AEL, AET, AFG, AFI, AFO, AFR, AFS, AFY, AHT, AST, ASV , ATN, ATO, ATS, ATV, AWO, AWW, BCT, BEA, BEC, BIK, BOF, BOG, BPH, BRE, BSV, CAN, CAS, CFI, CGF, CGS, -CHI, -CLO, CON, CZP , DAC, DFO, DOH, DON, EMT, EON, ESV, ETR, EUO, EZT, FAR, FAU, FER, FRA, GIU, GME, GON, HEU, IFR, IMF, ISV, ITH, ITR, IWR, IWS , IWV, IWW, JBW, JRY, LAU, LIO, -LIT, LOS, LOV, LTF, LTL, LTN, SEA, MAZ, MEI, HONEY, MEP, MFI, MFS, MOR, MOZ, MRE, MSE, MSO, MTF, MTN, MTT, MTW, MWW, NAB, NAT, NES, NON, NPO, OBW, OFF, OSI, OSO, -PAR, PON, -RON, RRO, RSN, RTE, RUT, RWR, RWY, SAO, SAS, SBE, SBS, SBT, SFE, SFF, SFG, SFH, SFN, SFO, SFS, SGT, SOD, SOF, SOS, SSF, SSY, STF, STI, STO, STT, STW, -SVR, SZR, TER , TOL, TON, TUN, UOS, UOZ, USI, UTL, VET, VFI, VSV, WEI or -WEN (as defined by the “Structure Commission of the International Zeolite Association”) or is a mixture of any two or more of these. [00027] Preferred zeolitic or non-zeolitic molecular sieves are selected from the group consisting of BEA, FAU, FER, MFI, MFS, MOR, STI, SZR and mixtures of any two or more of these. [00028] Especially preferred zeolitic or non-zeolitic molecular sieves are selected from the group consisting of BEA, FER, MFI, STI and mixtures of any two or more of these. Especially preferred zeolitic molecular sieves are ZSM-5, beta, ferrierite and mixtures of any two or more of these. [00029] Although natural zeolytic molecular sieves can be used in the present invention, we prefer synthetic aluminosilicate molecular sieve having a silica to alumina ratio of 10 or greater, for example 15 to 150, 20 to 60 or 25 to 40 for thermal stability improved. [00030] In an alternative embodiment, the zeolitic molecular sieve or the non-zeolitic molecular sieve is an isoform form containing one or more frame metal substituents. In this embodiment, the or each replacement frame metal can be selected from the group consisting of As, B, Be, Ce, Co, Cu, Fe, Ga, Ge, Li, Mg, Mn, Zn and Zr, with Ce, Cu and Fe. Again, preferred isomorphic zeolitic or non-zeolitic molecular sieves are selected from the group consisting of BEA, FER, MFI, NSI, STI and mixtures of any two or more of these, with BEA including Fe in its frame being especially preferred. It will be understood that in the process of manufacturing such isoform forms containing one or more substituting frame metals, the or each metal may be present in the final product either only in the frame or in the ion-exchanged frame. [00031] Ratios of silica to alumina in isomorphic forms containing one or more substituting frame metals may be >25, such as 30 to 100 or 40 to 70. In contrast, the isomorphic form may have a silica to alumina ratio of > 20, such as from 30 to 200 or 50 to 100. [00032] In a preferred embodiment, the non-zeolytic molecular sieve is an aluminophosphate, including AlPOs, metal-substituted AlPOs (MeAlPOs), silicoaluminophosphates (SAPOs) or metal-substituted silicoaluminophosphates (MeAPSOs). [00033] Proportions of silica to alumina of aluminophosphates are generally much lower than those of aluminosilicate zeolites sharing the same frame type code. Typically, the silica to alumina ratio of aluminophosphates is <1.0, but it can be <0.5 or even <0.3. [00034] The ceria component can optionally be stabilized with at least one non-cerium element to increase the thermal stability of the ceria. Suitable ceria stabilizers include zirconium, lanthanides and mixtures of any two or more of these. Lanthanide stabilizers include La, Nd, Pr, Gd and mixtures of any two or more of these. The weight ratio of CeO2:ZrO2 can be e.g. 80:20 or 20:80. Commercially available materials include 30% by weight CeO2, 63% ZrO2, 5% Nd2O3, 2% La2O3; and 40% CeO2, 50% ZrO2, 4% La2O3, 4% Nd2O3 and 2% Y2O3. [00035] Generally speaking, the at least one metal may be present: (a) throughout the extruded solid body, i.e. the at least one metal is present in the extrudate composition; (b) present in a higher concentration on a surface of the extruded solid body; and/or (c) carried in one or more coating layer(s) on a surface of the extruded solid body in features (iii), (iv) and (v) it is different that the at least one metal present in each of( s) location(s) in (a), (b) and (c). Thus according to the invention the at least one metal may be present at location (b), (c), (a) plus (b), (a) plus (c) or (a) plus (b) plus (c ). If the at least one metal is present in (a) and (b), (a) and (c) or (a), (b) and (c), the at least one metal at each location may be the same or different . [00036] If the at least one metal is present in location (a), ie throughout the extruded solid body, the at least one metal can be associated with the zeolitic molecular sieve, the non-zeolitic molecular sieve or a mixture of any two or more of these. An example of "associated with" includes being ion-exchanged with the zeolitic molecular sieve component, the non-zeolitic molecular sieve component, or any one or both of the zeolitic molecular sieve and non-zeolitic molecular sieve components in the mixture. It is also possible in mixtures of two or more molecular sieves to have at least one metal associated with one molecular sieve and not the other. For example, a first molecular sieve can be ion-exchanged with copper, dried and calcined and then mixed with a different molecular sieve not associated with additional metal. [00037] It has been found that by the ion exchange of zeolites, e.g. Beta-zeolite, with a transition metal, e.g. iron, the thermal stability of the oxidation catalyst can be improved, and also the activity as can be seen in the accompanying Examples. [00038] Alternatively, one of the two molecular sieves in a mixture may be associated, e.g. ion-exchanged, with a first at least one metal and then a second at least one metal may be added in the extrudate composition. [00039] At least one metal(s) suitable to associate with the or each molecular sieve component may be selected individually from the group consisting of a transition metal, a lanthanide or a mixture of any two or more of these. Suitable transition metals include Group IB metals, Group IVB metals, Group VB metals, Group VIIB metals, and Group VIII metals. Preferably the at least one transition metal is selected from the group consisting of Fe, Cu, Ce, Hf, La, Mn and V and mixtures of any two or more of these. The lanthanide metal can be La, Pr, Ce and mixtures of two or more of these. [00040] The total metal content in the at least one metal associated with the or each molecular sieve component is from 0.1% to 20% by weight, such as from 1% to 9% by weight. [00041] The at least one metal present throughout the extruded solid body but not associated with the or each molecular sieve; in most of the at least one metal located on the surface of the extruded solid body; in one or more coating layer(s) on the surface of the extruded solid body; or at the highest concentration on the surface of the extruded solid body may be selected from the group consisting of a transition metal, a lanthanide metal or a mixture of any two or more of these. [00042] Suitable coatings to support catalytic metals for use in the present invention include one or more of alumina (Al2O3), especially Y-alumina, silica (SÍO2), titania (TIO2), ceria (CeO2), zirconia (ZrO2), vanadia (V2O5), lantana (La2O3) and zeolites. The ceria and alumina can optionally be stabilized using the same stabilizers used for the extruded solid body. It has been shown that the presence of molecular sieve (zeolite) in one or more coating layers, in addition to the presence of molecular sieve in the extruded solid body, beneficially improves hydrocarbon conversion relative to a non-molecular sieve oxidation catalyst in a or more coating layers, regardless of the molecular sieve present in the extruded solid body (see Example 3B). Therefore the presence of molecular sieve in one or more coating layers is preferred. Suitable catalytic metals include one or more precious metals (Au, Ag and platinum group metals including Pt, Pd and Rh)). [00043] Techniques for locating at least one metal in higher concentration on the surface of the extruded solid body include impregnation, preferably thickened impregnation, i.e. an impregnation medium thickened with a rheology modifier. Drying methods can also be used to concentrate metals onto an extruded solid body surface. For example, a so-called "eggshell" technique, in which metals are concentrated on the surface, can be performed by drying the extruded solid body impregnated relatively slowly so that the metals are deposited on the surface by capillary action. Special choices of salts and pH conditions can also be used to direct metal deposition, eg by determining the isoelectric point of the extruded solid body and then using the correct combination of pH and metal salts to benefit from an electrostatic attraction between cations or anions in the metal and in the extruded solid body. [00044] Suitable transition metals include a Group IB metal and a Group VIII metal. Preferably, the or each precious metal is selected from the group consisting of Pt, Pd, Au, Ag, Ir, Ru, Rh, Os and mixtures of any two or more thereof; and suitable lanthanide metals can be La, Pr or Ce or mixtures of any two or more thereof. [00045] The total metal content in the entire extruded solid body, but not associated with the or each molecular sieve component; located on the surface of the extruded solid body; and/or the highest concentration on the surface of the extruded solid body may be from 0.1% to 20% by weight, such as from 1% to 9% by weight. [00046] The total metal content of the extruded solid body, i.e. including any metal associated with the or each molecular sieve, may be from 0.1% to 25% by weight, such as from 1% to 15% by weight. [00047] The total metal content of the catalyst as a whole, including one or more coating layer(s) on a surface of the extruded solid body comprising at least one metal, may be from 0.1% to 30% by weight, such as from 1% to 25% by weight. [00048] The content of the at least one binder/matrix component can be >15% by weight, >20% by weight, >30% by weight, >35% by weight, >40% by weight, >45% by weight , >50% by weight, >55% by weight, >60% by weight, >65% by weight or >70% by weight, >75% by weight, >80% by weight, >85% by weight or > 90% by weight. The spinel content can be >10% by weight, >15% by weight, >20% by weight, >30% by weight, >35% by weight, >40% by weight, >45% by weight , >50% by weight, >55% by weight, >60% by weight, >65% by weight or >70% by weight. [00050] The content of the total molecular sieve(s) may be >10% by weight, >15% by weight, >20% by weight, >30% by weight, >35% by weight , >40% by weight, >45% by weight, >50% by weight, >55% by weight, >60% by weight, >65% by weight or >70% by weight, >75% by weight, > 80% by weight or >85% by weight. The content of the optionally stabilized ceria can be >5% by weight, >10% by weight, >15% by weight, >20% by weight, >30% by weight, >35% by weight, >40% by weight, >45% by weight, >50% by weight, >55% by weight, >60% by weight, >65% by weight or >70% by weight. The inorganic fiber content can be >5% by weight, >10% by weight, >15% by weight or >20% by weight. [00053] In one embodiment the extruded solid body consists essentially of: 10-100% by weight of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, a spinel, an optionally doped alumina, a silica source, titania, zirconia, titania-zirconia, zirconite and mixtures of any two or more of these; 50-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof, each optionally containing one or more metals; and 0-25% by weight of inorganic fibers. [00054] Other embodiments may use an extruded solid body consisting essentially of: 10-37% by weight cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, an optionally doped alumina, a spinel, a silica source, titania , zirconia, titania-zirconia, zirconite and mixtures of any two or more of these; 6088% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, each optionally containing one or more metals; and 0-20% by weight of inorganic fibers; or: 15-30% by weight of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, an optionally doped alumina, a spinel, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more thereof; 2-20% by weight of a silica source; 50-81% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, each optionally containing one or more metals; and 2-10% by weight of inorganic fibers. [00055] In another embodiment suitable for use in diesel oxidation catalysts, the extruded solid body may consist essentially of: 10-100% by weight of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, an optionally doped alumina, a spinel, a source of silica, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more of these; 5-50% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, each optionally containing one or more metals; 20-80% by weight of optionally stabilized ceria; and 0-25% by weight of inorganic fibers. Preferred embodiments contain zeolites and inorganic fibers. [00056] In the development of extruded solid bodies for use in NOx capture catalysts according to the present invention, we have found the lack of strength in the extruded solid body in the composition: 69% by weight of CeO2, and 23% by weight of Y-Al2O3 and 8% by weight of glass fibers. Current proposals to increase strength include precalcination of the CeO2 material to reduce surface loss during calcinations of the “green” extruded solid body; increasing the alumina content to more than 50%; changing the particle size of the alumina (e.g. from commercially available Pural™ to Disperal™) and/or the optionally stabilized ceria; adding an inert binder to increase mechanical stability e.g. a clay; use of a different alumina e.g. an alumina sol; testing of other binding systems e.g. TiO2 suns, CeO2 suns; cerium acetate; zirconium acetate; pH optimization; and adding surface modifiers e.g. aluminum salts or other organic surfactants. In preliminary tests we have verified that the presence of can affect NOx capture performance. Research is ongoing and this option will be further investigated. However, in one embodiment the content of a silica source will be reduced or completely removed. [00057] In more specific examples according to the present invention: (i) a diesel oxidation catalyst comprises an extruded solid body in the direct flow configuration essentially consisting of: 15-70% by weight of cordierite, nitrides, carbides, borides , intermetallics, lithium aluminosilicate, a spinel, an optionally doped alumina, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more of these; 0-20% by weight of a silica source; 50-81% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, each optionally containing one or more metals; and 0-20% by weight inorganic fibers, said extruded solid catalyst body being coated with a first inner layer comprising Pt; Pd; Au; Pt and Pd; Pd or Au transported(s); and a second outer catalyst layer comprising Pt; Pd; Au; Pt and Pd; Pd or Au transported(s); and provided that if the metal(s) present in the inner layer and outer layer are the same, the metal loadings in the inner layer and outer layer will be different; and (ii) a catalyzed soot filter comprises an extruded solid body in the wall flow filter configuration consisting essentially of: 15-70% by weight of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, a spinel, an optionally doped alumina, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more of these; 0-20% by weight of a silica source; 550% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, each optionally containing one or more metals; 20-80% by weight of optionally stabilized ceria; and 0-20% by weight of inorganic fibers, which extruded solid catalyst body is coated with one or more layer(s) comprising carried at least one precious metal and combinations of any two or more precious metals. [00058] According to another aspect, the invention provides a process for manufacturing an oxidation catalyst according to the invention comprising the steps of: forming a solid extruded body by mixing powdered starting materials of: at least one binder component / matrix or a precursor of one or more thereof; zeolitic molecular sieve, non-zeolitic molecular sieve or a mixture of any two or more thereof which zeolitic molecular sieve, non-zeolitic molecular sieve or mixture of zeolitic and non-zeolitic molecular sieves is optionally associated with at least one metal; an optionally stabilized ceria; and an at least one optional metal compound; with optional organic fibers; and optionally adding an organic auxiliary agent; processing by mixing and/or kneading in an acidic or alkaline aqueous solution optionally containing a metal salt of at least one metal in a plastic compound to form a mixture; extruding the mixture into a catalyst body, drying the catalyst body and calcining to form a solid extruded body; selecting quantitative proportions of starting materials such that the extruded solid body comprises 10-100% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 080% by weight of optionally stabilized ceria and optionally at least one metal, and impregnating a surface of the solid extruded body with at least one metal and/or coating a surface of the solid extruded body with at least one coating layer(s) containing at least one metal. [00059] Typically, a cement is used impermeably to plug the ends of channels in a solid monolithic substrate to form the wall flow filter, e.g. as disclosed in EP 1837063. [00060] Very generally, the production of an extruded solid body, a binder, a viscosity enhancing organic compound and a liquid to convert the material by mixing into a homogeneous paste are added in the binder/matrix component or in a precursor and sieve thereof molecular, optional optionally stabilized ceria, optional inorganic fibers and at least one optional metal compound, and the mixture is compacted in a mixing or kneading apparatus or an extruder. The blends have organic additives such as binders, plasticizers, surfactants, lubricants, dispersants and processing aids to enhance wetting and therefore produce a uniform batch. The resulting plastic material is then molded, in particular using an extrusion press or an extruder including an extrusion die, and the resulting moldings are dried and calcined. Organic additives are “burned” during calcination of the extruded solid body. [00061] The at least one binder/matrix component can be selected from the group consisting of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, a spinel, an optionally doped alumina, a silica source, titania, zirconia, titania -zirconia, zirconite and mixtures of any two or more of these. An alumina precursor that is aluminum hydroxide or boehmite can be used. If an aluminum oxide is used, to ensure agglutination with the aluminum oxide, it is advantageous to add an aqueous solution of a water-soluble metal salt in the aluminum oxide or aluminum oxide precursor substance before adding the other materials initials. [00062] In embodiments, the silica source can be selected from the group consisting of a silica, a silica sol, quartz, fused or amorphous silica, sodium silicate, an amorphous aluminosilicate, an alkoxysilane, a silicone resin binder , a clay, talc, or a mixture of any two or more of these. [00063] In a special embodiment, the silica source is a silicone resin binder and a solvent for the silicone resin binder is isopropyl alcohol or a dibasic ester. [00064] An embodiment of the process according to the present invention comprises the step of first mixing an optionally doped alumina or a precursor thereof with the solution and subsequently mixing the zeolitic molecular sieve, non-zeolitic molecular sieve or a mixture of any two or more of these and the inorganic fibers. [00065] The organic auxiliary agent for use in the process according to the present invention may be one or more selected from the group consisting of a cellulose derivative, an organic plasticizer, a lubricant and a water-soluble resin. Examples of suitable cellulose derivatives include cellulose ethers selected from the group consisting of methyl-cellulose, ethyl-cellulose, carboxy-methyl-cellulose, ethyl-hydroxy-ethyl-cellulose, hydroxy-ethyl-cellulose, hydroxy-propyl-cellulose, methyl -hydroxy-ethyl-cellulose, methyl-hydroxy-propyl-cellulose and combinations of any two or more thereof. Cellulose derivatives increase the porosity of the final product, which is beneficial for the catalytic activity of the solid catalyst body. The cellulose initially swells in the aqueous suspension, but it is eventually removed during the calcination process. [00066] The organic plasticizer for use in the process of the present invention is selected from the group consisting of poly(vinyl-alcohol), poly(vinyl-butyral), an ionomer, acrylics, ethylene/acrylic acid copolymer, polyurethane, a thermoplastic elastomer , a relatively low molecular weight polyester, flaxseed oil, a ricinoleate and combinations of two or more of these. [00067] The water-soluble resin can be a polyacrylate. [00068] The lubricant for use in the process according to the present invention is selected from at least one of the group consisting of ethylene glycol, stearic acid, sodium stearate, glycerin and glycols. [00069] Depending on the composition of the extrudate composition, the pH can be acidic or alkaline. If the process uses an acidic aqueous solution, the pH value of the solution can be between 3 and 4. Desirably, acetic acid is used to acidify the solution. [00070] If the process uses an aqueous alkaline solution, the pH value of the solution can be between 8 and 9. Ammonia can be used to adjust the pH to the alkaline side. [00071] According to another aspect, the invention provides a method of treating exhaust gaseous emissions of internal combustion engines from a stationary source or a vehicle, which method comprises contacting the exhaust gas with an oxidation catalyst according to the invention. The temperature at which the exhaust gas contacts the catalyst is preferably >100°C, such as >150°C, >175°C, >200°C, >225°C, >250°C, >275°C or >300°C. Preferably, the temperature at which the exhaust gas contacts the catalyst is <600°C, such as <550°C, <525°C or <500°C. [00072] According to another aspect, there is provided an exhaust system for an internal combustion engine, which exhaust system comprises an oxidation catalyst according to the invention. The internal combustion engine can be a compression ignition engine or a positive ignition engine. A positive ignition engine is typically powered with fuel such as gasoline fuel, but other fuels can be used including gasoline fuel blended with oxygen compounds including methanol and/or ethanol, liquefied petroleum gas or compressed natural gas. Compression ignition engines can be powered with fuel such as diesel fuel, diesel fuel blends and biodiesel or Fischer-Tropsch derived fuels, biodiesel as such or natural gas as such. Modern compression-ignition engines including those known as the Dilution Controlled Combustion System (DCCS), for example Toyota's Smokeless Rich Combustion concept. Emissions from Homogeneous Charge Compression Ignition (HCCI) engines can also be treated. In particular, modern engines can be treated in which substantially all of the combustion fuel is injected into a combustion chamber before combustion starts. [00073] According to another aspect of the invention, there is provided a vehicle comprising an internal combustion engine (optionally as defined above) and an exhaust system according to the invention. [00074] In order that the invention may be more fully understood, the following Examples are provided by way of illustration only and with reference to the accompanying drawings in which: Figure 1 is a graph comparing % hydrocarbon conversion activity a diesel oxidation catalyst aged at 650°C in accordance with Examples 3A and 3B with similarly aged Comparative diesel oxidation catalysts in accordance with Examples 5A and 5B in the test procedure described in Example 6; Figure 2 is a graph comparing % hydrocarbon conversion activity plotted against the temperature of a diesel oxidation catalyst aged at 800°C from Examples 3A and 3B and similarly aged Comparative diesel oxidation catalysts from Examples 5A and 5B in the procedure test described in Example 6; Figure 3 is a graph comparing % hydrocarbon conversion activity plotted against the temperature of a diesel oxidation catalyst aged at 650°C according to Examples 3A and 4 compared to an uncoated cordierite direct flow substrate; Figure 4 is a graph comparing carbon monoxide (CO) conversion activity and total hydrocarbon (THC) conversion activity for 3C, 5C and 5D examples plotted against temperature; Figure 5 is a graph comparing the pore volume and porosity of various V2O5/WOx-TiO2 filter materials prepared using various pore modifiers against the Reference product used in a straight-flow configuration; and Figure 6 is a graph plotting pore volume against pore radius for numerous pore modifiers against V2O5/WOx-TiO2 Reference and a commercially available wall flow filter substrate. EXAMPLE 1 - EXTRUDED MONOLITH ZEOLITE SUBSTRATE CONTAINING H-BETA ZEOLITE [00075] An extruded monolithic zeolite substrate was prepared according to methods similar to those disclosed in US 7,507,684. Commercially available beta zeolite powder in hydrogen form is mixed with glass fibers, Kaolin filler and synthetic bohemite powder (Pural SB) and is processed in an aqueous solution with a pH value of 5-6 into a moldable clay and flowable by blending with cellulose (CMC-QP10000H), the plasticizer Zusoplast (a trademark of Zschimmer & Schwarz GmbH & Co KG) and the organic auxiliary agent PEO Alkox (a poly(ethylene oxide)). The quantitative proportions of the starting materials are selected in such a way that the active material of the finished solid catalyst body contains 69% by weight of zeolite, 23% by weight of Y-Al2O3, 5% by weight of glass fibers and 3% by weight of kaolin. The moldable mixture is extruded into a 2.54 cm diameter x 7.62 cm long direct flow honeycomb catalyst body, ie with continuous channels and with a circular cross section exhibiting a cell density of 62 cpcq ( cells per square centimeter). Subsequently, the catalyst body is freeze-dried for 1 hour at 0.2 kPa according to the method described in WO 2009/080155 (the entire contents of which are hereby incorporated by reference) and calcined at a temperature of 580°C to form a solid catalyst body. EXAMPLE 2 - EXTRUDED MONOLITH ZEOLITE SUTRACT CONTAINING FE-BETA ZEOLITE [00076] Powdered beta zeolite in the form of commercially available hydrogen is mixed with iron hydroxide, glass fibers, a low alkaline clay filler and powdered synthetic bohemite (Pural SB) and is processed into an aqueous solution with a value of pH 5-6 in a moldable and flowable clay. When the blend is well plasticized, cellulose is added at 8% by weight based on 100% of the total inorganic solids content. The quantitative proportions of the starting materials are selected in such a way that the active material of the finished solid catalyst body contains 55% by weight of zeolite, 25% by weight of clay, 7% by weight of y-Al2O, 3.8% by weight of glass fibers and 5% by weight of iron and iron compound. The moldable mixture is extruded into a 2.54 cm diameter x 7.62 cm long direct flow honeycomb catalyst body, ie with continuous channels and with a circular cross section exhibiting a cell density of 62 cpcq ( cells per square centimeter). Subsequently, the catalyst body is freeze-dried for 1 hour at 0.2 kPa according to the method described in WO 2009/080155 (the entire contents of which are hereby incorporated by reference) and reductively calcined according to the method described in Application Patent No. PCT/EP2010/005140 filed August 21, 2010 (the entire contents of which are incorporated herein by reference) at a temperature of 580°C to form a solid catalyst body. It is verified that by using the method described at least some of the iron introduced into the mixture becomes iron-exchanged with the zeolite. EXAMPLE 3 - TWO LAYER DIESEL OXIDATION CATALYST ON MONOLITHIC EXTRUDED ZEOLITE SUBSTRATE FROM EXAMPLE 1 [00077] A 2.54 cm x 7.62 cm beta direct flow zeolite sample with 62 cpcq prepared according to Example 1 was coated with reactive coating (according to the techniques of WO 99/47260) with a first layer comprising a reactive coating mixture of Pt and Pd/Y-alumina (Example 3A); or a first layer comprising a mixture of Pt and Pd/y-alumina and H-beta zeolite (Example 3B). The resulting products were dried and calcined at 600°C. A second layer of Pt/Y-alumina reactive coating overlying the first layer was applied to each of Examples 3A and 3B and the resulting coated portion was dried then calcined at 600°C. The ratio of precious metals present was 2Pt:Pd with a total precious metal loading of 6.41 g.cm-3. [00078] A separate monolith of 12.70 cm x 15.24 cm of 62 cpcq was coated with a two-layer catalyst as described in example 3B for engine testing in Example 7. The 12.70 cm x 15 catalyst, 24 cm was aged at 800°C for 50 hours in 5% H2O and was designated Example 3C. EXAMPLE 4 - TWO-LAYER DIESEL OXIDATION CATALYST ON EXTRUDED MONOLITHIC ZEOLITE SUBSTRATE FROM EXAMPLE 2 [00079] Sample of zeolite Fe-beta 5% by weight ion-exchanged, direct flow, 2.54 cm x 7.62 cm, 62 cpcq, from Example 2, was coated with a two-layer catalyst as described in example 3A. This sample was aged in air at 650°C for 64 hours in 5% H2O. COMPARATIVE EXAMPLE 5 - TWO-LAYER DIESEL OXIDATION CATALYST ON MONOLITHIC CORDIERITE SUBSTRATE [00080] Two-layer catalysts identical to Examples 3A and 3B were prepared using 62 cpcq cordierite monolithic substrate in place of extruded zeolite monolithic substrates and 2.54 cm x 7.62 cm cores were cut from these (Comparative Examples 5A and 5B respectively). [00081] Monolithic substrates of 12.70 cm x 15.24 cm, 62 cpcq, separated, were coated with a two-layer catalyst as described in examples 3A and 3B for engine testing in Example 7. Catalysts of 12, 70 cm x 15.24 cm were aged at 800°C for 50 hours in 5% H2O and designated 5C and 5D respectively. EXAMPLE 6 - DIESEL OXIDATION CATALYST LABORATORY TEST [00082] The 2.54 cm x 7.62 cm samples of each of Examples 3A and 3B and Comparative Examples 4A and 4B were aged in air at either 650°C for 64 hours in 5% H2O (results shown in Figure 1); than at 800°C for 50 hours in 5% H2O (results shown in Figure 2). [00083] Each sample was tested on a synthetic catalyst activity laboratory test platform (SCAT), using the following synthetic regular lean conditions: Unit Displacement (Swept Volume, SV) = 60K, C10H22 = 100 ppm Cl, CO = 200 ppm, NOx = 200 ppm, O2 = 12%, CO2 = 5%, H2O = 5% in N2; temperature rise from 120°C to 400°C to 40°C per minute. [00084] From Figures 1 and 2 it can be seen that both Examples 3A and 3B show significantly better catalyst conversion activity at lower temperatures e.g. 120-240°C than either of Comparative Examples 5A and 5B. It can also be seen that between Examples 3A and 3B, Example 3B, which contains zeolite H-beta inside, the first layer in addition to the extruded substrate, performs better than that of Example 3A without zeolite H-beta in the inner reactive coating layer. [00085] From Figure 3 it can be seen that the catalyst of Example 4 has a higher hydrocarbon conversion activity than the catalyst of Example 3A. The inventors conclude that the catalyst comprising the extruded solid body including ionically exchanged Beta zeolite Fe ion maintains the aged activity more effectively than the extruded solid body as the Beta zeolite is not metallized (H-Beta). EXAMPLE 7 - DIESEL OXIDATION CATALYST TEST IN ENGINE [00086] The catalysts of Example 3C and Examples 5C and 5D were in turn tested by coupling them to the exhaust system of a 2007 certified 6.4 liter light-heavy diesel engine mounted on a bench fitted with a bench-mounted dynamometer. motor. The engine was operated at a speed and torque rating sufficient to produce a catalyst inlet temperature of 150°C (in displacement of 100 K/h). The torque was increased at a linear rate sufficient to increase the catalyst inlet temperature by 15°C per minute for a total inlet temperature of 350°C (in displacement of 140 K/h). [00087] The CO % conversion and the total hydrocarbon conversion (THC) % over the catalyst were determined during the course of the tests and are plotted against the temperature in accompanying Figure 4 from which it can be seen that the Example 5D catalyst including zeolite in its reactive coating underlying layer shows initially reasonable THC conversion at 150°C, which however drops below Example 5C's THC conversion at 200°C before regaining parity for Example 5C at above 275°C. The inventors interpret that the initial THC conversion of Example 5D to Example 5C results from adsorption of HC at low temperature. However, it can be seen that the THC conversion of Example 3C according to the invention is better than that of either Example 5C or 5D, which does not include zeolite in the extruded substrate body. [00088] The CO conversion of Example 3C according to the invention is broadly similar to that of Example 5C, with slightly better activity observed at low temperature. EXAMPLE 8 - EXTRUDED MONOLITH ZEOLITE SUBSTRATE [00089] An alternative extruded zeolite monolithic substrate to Example 1 was prepared according to methods similar to those disclosed in US 7,507,684. Powdered zeolite in the form of hydrogen commercially (Tosoh) is mixed with glass fibers (Vetrotex 4.5 mm (Saint-Gobain)), low alkaline clay filler and powdered synthetic bohemite (Pural SB) and is processed into a solution aqueous with a pH value of 5-6 in a flowable moldable clay by mixing with 8% by weight of cellulose (based on total inorganic solids content) (CVP-M-5280 (Dow Wolff Cellulosics)). The quantitative proportions of the starting materials are selected in such a way that the active material of the finished solid catalyst body contains 60% by weight of zeolite, 25% by weight of clay, 7% by weight of Y-Al2O3 and 8% by weight of glass fibers. The moldable mixture is extruded into a direct flow honeycomb catalyst body, i.e. with continuous channels and with a circular cross section at a desired cell density. Subsequently, the catalyst body is freeze-dried for 1 hour at 0.2 kPa according to the method described in WO 2009/080155 (the entire contents of which are hereby incorporated by reference) and calcined at a temperature of 580°C to form a solid catalyst body. EXAMPLE 9 - EXTRUDED V2O5/WOx-TiO2 FILTER [00090] An extruded Reference V2O5/WOx-TiO2 solid body was prepared similarly to Examples 1 and 5 by mixing components A, B, F and S as shown in Table 1 with water to prepare a dough paste. Additives H (pore modifiers) were added and the material was kneaded for 10 min to disperse the pore modifiers. The resulting composition was extruded, dried and calcined as described in Examples 1, 2 and 7. It should be noted that the percentage amounts of inorganic solids present in the final calcined article is 100%. Amounts of additives (here H and S) which are removed by combustion during calcination are given in % by weight relative to the 100% inorganic solids content. Table 1 A1 = TiW (98.9%, MC 10/Crystal) A2 = AMV V2O5 (78% V2O5, GFE) B1 = Bentonite (90%, ACE/Mizuka) B2 = Kaolin (97.9% TK0177/Thiele) B3 = SiO2 (100%, Tixosil/Novus) F1 = Fiberglass (Vetrotex 4.5 mm/Saint Gobain) H1 = Cellulose (QP10000H/Nordmann) H2 = PEO (Alkox/Alroko) H3 = Zusoplast (Zschimmer&Schwarz) S1 = MEA (Imhoff & Stahl) S2 = NH3 S3 = C3H6O3 (Fauth) [00091] The following pore modifiers were used in place of the Extrusion Additives H1, H2 and H3 in Table 1, with amounts being relative to the total weight of inorganic solid in the recipe in Table 1. Table 2 [00092] Porosity and pore volume and pore radius can be measured e.g. using mercury intrusion porosimetry. [00093] The input results in Table 2 including pore volume and porosity are also represented in Figure 5. It can be seen from these results that the porosity and pore volume of the Reference can be increased by the proper selection of pore modifiers so that an extruded solid body prepared using such pore modifiers can be used in the manufacture of wall flow filters. [00094] These results are generic for increasing porosity, pore volume etc. independent properties of the active components of the solid extruded body. That is, although the increase in porosity and pore volume etc. of this Example 6 is illustrated using V2O5/WOx-TiO2 active materials, the principles of porosity increase and pore volume etc. disclosed in this Example 6 are applicable to the extrusion of any active material, eg an extruded solid body for use in a gasoline soot filter comprising a three-way catalyst, because the pore modifiers are burned in the calcining process leaving the active materials and the loads etc. remaining as inorganic solids. [00095] Figure 6 compares the pore volume of a different Reference with extruded V2O5/WOx-TiO2 materials prepared using other pore modifiers shown in Table 2 also compared to a commercially available wall flow filter (NGK) . It can be seen from the graph that the inclusion of pore modifiers has improved the porosity and pore volume of the Reference extruded solid body so that the materials have properties approaching those of commercially available wall flow filters. EXAMPLE 10 - EXTRUDED CATALYSED SOOT FILTER [00096] This is a prophetic example. A catalyzed wall flow monolithic filter substrate can be prepared as follows. An appropriate amount of CeO2-ZrO2 mixed oxide can be mixed with glass fibers, powdered syntactic bohemite (Pural SB) and beta zeolite and processed in an aqueous solution with a pH value of 3.5 into a capable moldable clay. flowable containing 1.2 wt% cellulose (CMC-QP10000H), 1.0 wt% organic PEO Alkox auxiliary agent (a poly(ethylene oxide) and 13 wt% of a mixture of Rettenmaier pore modifiers BC200 and polyacrylonitrile fibers (PAN) Quantitative proportions of starting materials can be selected in such a way that the active material of the finished solid catalyst body contains 25% by weight of CeO2-ZrO2, 15% by weight of zeolite beta, 52% by weight of y-Al2O3 and 8% by weight of glass fibers. The moldable mixture can then be extruded into a honeycomb catalyst body with continuous channels and a circular cross section exhibiting a cell density of 46 cpcq (cells per square centimeter). Subsequently, the catalyst body can be freeze dried for 1 hour at 0.2 kPa according to the method described in WO 2009/080155 (the entire contents of which are hereby incorporated by reference) and calcined at a temperature of 580°C to form a solid catalyst body. Typically, the resulting product would be expected to have an average pore size of approximately 10 µm. [00097] The extruded direct flow monolithic substrate comprising a plurality of channels can be transformed into a wall flow filter arrangement whereby a plurality of first channels is occluded at an upstream end and a plurality of second channels unobstructed at the the upstream end is occluded at a downstream end, the arrangement of the first and second channels being such that laterally and vertically adjacent channels are occluded at opposite ends in the appearance of a chessboard by inserting substantially gas-impermeable plugs at the ends of the channels in the desired pattern according to EP 1837063 (the entire contents of which are hereby incorporated by reference). This filter arrangement is also disclosed in SAE 810114 (the entire contents of which are incorporated herein by reference). The calcined extruded monolithic substrate may be coated with a reactive coating comprising Pt-Pd according to the methods disclosed in WO 99/47260 or PCT/GB2011/050005 filed January 4, 2011. The last method comprises the steps of: ( i) maintaining a monolithic honeycomb substrate substantially vertically; (ii) introducing a predetermined volume of liquid into the substrate via the open ends of channels at a lower end of the substrate; (iii) sealingly retain the liquid introduced into the substrate; (iv) inverting the substrate containing the trapped liquid; and (v) applying a vacuum to the open ends of the substrate at the lower, inverted end of the substrate to draw liquid along the substrate channels. [00098] For the avoidance of doubt, the entire contents of any and all documents cited herein are hereby incorporated by reference.
权利要求:
Claims (14) [0001] 1. Oxidation catalyst, comprising an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a synthetic aluminosilicate based zeolitic molecular sieve or a mixture of any two or more of these sieves, each having an open pore structure with 10 or more rings as its largest pore opening and a ratio of silica for alumina from 10 to 150; and, 0-80% by weight of optionally stabilized ceria, characterized in that it comprises at least one precious metal and optionally at least one non-precious metal, where: (i) the majority of the at least one precious metal is located on a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface of the extruded solid body; (iii) at least one metal is present throughout the extruded solid body and is also present in a higher concentration on a surface of the extruded solid body; (iv) at least one metal is present throughout the extruded solid body and is also carried in one or more coating layer(s) on a surface of the extruded solid body; or (v) at least one metal is present throughout the extruded solid body, is present in a greater concentration on a surface of the extruded solid body, and is also carried in one or more layer(s) on the surface of the extruded solid body. [0002] 2. Catalyst according to claim 1, characterized in that the at least one metal present in each of: (a) throughout the extruded solid body; (b) present in a higher concentration on a surface of the extruded solid body; and (c) carried in one or more coating layer(s) on a surface of the extruded solid body in features (iii), (iv) and (v), is different from at least one metal present in the other(s). s) location(s). [0003] 3. Catalyst according to any one of claims 1 or 2, characterized in that the at least one non-precious metal is associated with the or each zeolitic molecular sieve. [0004] 4. Catalyst according to claim 3, characterized in that the or each of the at least one non-precious metal associated with the zeolitic molecular sieve contains one or more metals selected from the group consisting of Fe, Cu, Ce, Hf, La , Mn, V or a mixture of any two or more of these. [0005] 5. Catalyst according to any one of claims 1 to 4, characterized in that the at least one metal: in the majority of at least one metal located on the surface of the extruded solid body; in one or more coating layer(s) on the surface of the extruded solid body; or at the highest concentration at the surface of the extruded solid body comprises at least one metal selected from the group consisting of a Group VIII transition metal, a Group IB transition metal, a lanthanide metal and a mixture of any two or more of these. [0006] 6. Catalyst according to claim 5, characterized in that the at least one precious metal is selected from the group consisting of Pt, Pd, Au, Ag, Ir, Ru, Rh and Os. [0007] 7. Catalyst according to any one of claims 1 to 6, characterized in that the extruded solid body comprises: 10-95% by weight of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, an optionally alumina doped, a source of silica, titania, zirconia, titania-zirconia, zirconite, and mixtures of any two or more of these; 0-80% by weight spinel; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more of these, the or each optionally containing one or more metals; 0-80% by weight of optionally stabilized ceria; and 0-25% by weight of inorganic fibers. [0008] 8. Catalyst according to any one of claims 1 to 7, characterized in that the at least one binder/matrix component is selected from the group consisting of cordierite, nitrides, carbides, borides, intermetallics, lithium aluminum silicate, a spinel, an optionally doped alumina, a source of silica, titania, zirconia, titania-zirconia, zirconia, and mixtures of any two or more of these. [0009] 9. Catalyst according to any one of claims 1 to 8, characterized in that the zeolitic molecular sieve or the non-zeolitic molecular sieve has a type of code frame ABW, AEL, AET, AFG, AFI, AFO, AFR, AFS, AFY, AHT, AST, ASV, ATN, ATO, ATS, ATV, AWO, AWW, BCT, BEA, BEC, BIK, BOF, BOG, BPH, BRE, BSV, CAN, CAS, CFI, CGF, CGS, -CHI, -CLO, CON, CZP, DAC, DFO, DOH, DON, EMT, EON, ESV, ETR, EUO, EZT, FAR, FAU, FER, FRA, GIU, GME, GON, HEU, IFR, IMF, ISV, ITH, ITR, IWR, IWS, IWV, IWW, JBW, JRY, LAU, LIO, -LIT, LOS, LOV, LTF, LTL, LTN, SEA, MAZ, MEI, HONEY, MEP, MFI, MFS, MOR , MOZ, MRE, MSE, MSO, MTF, MTN, MTT, MTW, MWW, NAB, NAT, NES, NON, NPO, OBW, OFF, OSI, OSO, -PAR, PON, -RON, RRO, RSN, RTE , RUT, RWR, RWY, SAO, SAS, SBE, SBS, SBT, SFE, SFF, SFG, SFH, SFN, SFO, SFS, SGT, SOD, SOF, SOS, SSF, SSY, STF, STI, STO, STT , STW, - SVR, SZR, TER, TOL, TON, TUN, UOS, UOZ, USI, UTL, VET, VFI, VSV, WEI, or -WEN (as defined by the Structure Commission of the International Zeolite Association) and mixtures of any two or more of these [0010] 10. Catalyst according to claim 9, characterized in that the zeolitic molecular sieve or the non-zeolitic molecular sieve has a type of frame coded BEA, FER, MFI or is a mixture of any two or more of these. [0011] 11. Catalyst according to any one of claims 1 to 10, characterized in that the zeolitic molecular sieve is an aluminosilicate zeolite having a silica to alumina ratio of 10 or greater. [0012] 12. Process for manufacturing the oxidation catalyst as defined in any one of claims 1 to 11, characterized in that the process comprises the steps of: forming a solid extruded body by mixing powdered starting materials of: at least one component binder/matrix or a precursor of one or more thereof; zeolitic molecular sieve based on synthetic aluminosilicate or a mixture of any two or more of these sieves, each having an open pore structure with 10 or more rings as its largest pore opening and a silica to alumina ratio of 10 to 150, which zeolitic molecular sieve based on synthetic aluminosilicate or mixture of zeolitic molecular sieves based on synthetic aluminosilicate are optionally associated with at least one metal; an optionally stabilized ceria; and an at least one optional metal compound; with optional organic fibers; optionally adding an organic auxiliary agent; processing by mixing and/or kneading in an acidic or alkaline aqueous solution optionally containing a metal salt of at least one metal in a plastic compound to form a mixture; extruding the mixture into a catalyst body, drying the catalyst body and calcining to form a solid extruded body; selecting quantitative proportions of the starting materials such that the solid extruded body comprises 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a synthetic aluminosilicate based zeolitic molecular sieve or a mixture of any two or more of these sieves, each having an open pore structure with 10 or more rings as its largest pore opening and a ratio of silica for alumina from 10 to 150; and, 0-80% by weight of optionally stabilized ceria, and optionally at least one metal; and impregnating a surface of the solid extruded body with at least one precious metal and/or coating a surface of the solid extruded body with at least one coating layer(s) containing at least one precious metal. [0013] 13. Method for treating exhaust gas emissions from internal combustion engines from a stationary source or a vehicle, characterized in that the method comprises contacting the exhaust gas with an oxidation catalyst as defined in any one of the claims of 1 to 12. [0014] 14. Exhaust system for an internal combustion engine, characterized in that the exhaust system comprises the oxidation catalyst as defined in any one of claims 1 to 12.
类似技术:
公开号 | 公开日 | 专利标题 BR112012019030B1|2021-05-25|oxidation catalyst, process for manufacturing the oxidation catalyst, method for treating exhaust gas emissions from internal combustion engines, and exhaust system for an internal combustion engine GB2511178A|2014-08-27|NOx absorber catalysts
同族专利:
公开号 | 公开日 GB2477626B|2012-05-30| GB201101691D0|2011-03-16| US9040003B2|2015-05-26| EP2531278A1|2012-12-12| US8641993B2|2014-02-04| GB2479807A|2011-10-26| KR20180077344A|2018-07-06| CN102869429B|2016-07-13| HUE027305T2|2016-10-28| EP2531279A1|2012-12-12| US20140065042A1|2014-03-06| RU2505355C1|2014-01-27| KR101800699B1|2017-11-23| WO2011092519A1|2011-08-04| KR101940329B1|2019-01-18| JP6582078B2|2019-09-25| EP2539050B1|2015-09-02| EP2531280B1|2014-12-24| BR112012019018B1|2021-01-19| RU2012137278A|2014-03-10| DE102011010104A1|2011-08-04| CN102869429A|2013-01-09| KR20120125307A|2012-11-14| BR112012019020A2|2018-03-27| GB201101674D0|2011-03-16| RU2604231C1|2016-12-10| GB2511706A|2014-09-10| CN107008261B|2020-05-19| GB201410311D0|2014-07-23| EP2531277B1|2016-01-13| KR102040863B1|2019-11-06| KR20120139726A|2012-12-27| KR20170094462A|2017-08-17| GB201101730D0|2011-03-16| DE102011010107A1|2011-08-04| US20120117953A1|2012-05-17| EP2539050A1|2013-01-02| US20120110988A1|2012-05-10| KR20120125337A|2012-11-14| KR20180027618A|2018-03-14| KR101922734B1|2019-02-20| GB201411517D0|2014-08-13| GB2477628A|2011-08-10| GB2479808B|2014-11-12| GB2479807B|2012-12-05| CN104759275A|2015-07-08| DE202011110610U1|2015-07-02| WO2011092517A1|2011-08-04| CN107008261A|2017-08-04| KR101922733B1|2018-11-27| BR112012019009A2|2016-04-12| WO2011092521A1|2011-08-04| JP6312361B2|2018-04-18| JP2015077598A|2015-04-23| GB2479808A|2011-10-26| GB2511706B|2014-12-10| CN102821836A|2012-12-12| WO2011092525A1|2011-08-04| GB201101655D0|2011-03-16| DE102011010103A1|2011-08-04| US8263032B2|2012-09-11| US20120121486A1|2012-05-17| JP2018118248A|2018-08-02| GB2477628B|2014-11-12| JP2016064411A|2016-04-28| JP2013517936A|2013-05-20| CN102811797A|2012-12-05| JP5847094B2|2016-01-20| JP2015145008A|2015-08-13| JP2013517935A|2013-05-20| EP2531279B1|2015-10-07| KR102014664B1|2019-08-26| BR112012019036B1|2021-03-30| CN102811798A|2012-12-05| US9283519B2|2016-03-15| JP2013521996A|2013-06-13| JP6383683B2|2018-08-29| BR112012019030A2|2018-03-13| GB201101719D0|2011-03-16| JP2013518703A|2013-05-23| RU2570454C2|2015-12-10| JP2013517934A|2013-05-20| GB2477626A|2011-08-10| CN102811798B|2015-11-25| GB2477630A|2011-08-10| RU2012137242A|2014-03-10| RU2012137282A|2014-03-27| JP5784042B2|2015-09-24| US20120117952A1|2012-05-17| CN102834165A|2012-12-19| RU2570934C2|2015-12-20| BR112012019018A2|2020-08-04| EP2531278B1|2016-01-13| EP2531277A1|2012-12-12| CN104759275B|2018-11-09| US8609047B2|2013-12-17| US20140072490A1|2014-03-13| KR101922828B1|2018-11-27| JP5782050B2|2015-09-24| EP2531280A1|2012-12-12| HUE026104T2|2016-05-30| RU2012137280A|2014-03-10| GB2477630B|2014-11-12| JP6123095B2|2017-05-10| KR20120125336A|2012-11-14| JP5847095B2|2016-01-20| US20120122660A1|2012-05-17| CN102811797B|2017-02-15| JP2015077597A|2015-04-23| WO2011092523A1|2011-08-04| CN102821836B|2015-11-25| KR20120130327A|2012-11-30| US8815190B2|2014-08-26| DE102011010105A1|2011-08-04| HUE027335T2|2016-09-28| DE102011010106A1|2011-08-04| BR112012019036A2|2018-03-13| US8603423B2|2013-12-10| HUE026281T2|2016-05-30| RU2570883C2|2015-12-10|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3181231A|1963-08-06|1965-05-04|Union Carbide Corp|Molecular sieve-metal agglomerates and their preparation| US4510261A|1983-10-17|1985-04-09|W. R. Grace & Co.|Catalyst with high geometric surface area| US4735930A|1986-02-18|1988-04-05|Norton Company|Catalyst for the reduction of oxides of nitrogen| JPS6372342A|1986-09-13|1988-04-02|Sakai Chem Ind Co Ltd|Catalyst for removing nitrogen oxide| US5244852A|1988-11-18|1993-09-14|Corning Incorporated|Molecular sieve-palladium-platinum catalyst on a substrate| DE3940758C2|1989-12-09|1993-07-08|Degussa Ag, 6000 Frankfurt, De| US6869573B2|1990-11-09|2005-03-22|Ngk Insulators, Ltd.|Heater and catalytic converter| EP0593898B1|1992-10-20|1997-01-29|Corning Incorporated|Exhaust gas conversion method and apparatus using thermally stable zeolites| US6248684B1|1992-11-19|2001-06-19|Englehard Corporation|Zeolite-containing oxidation catalyst and method of use| US5552128A|1993-08-03|1996-09-03|Mobil Oil Corporation|Selective catalytic reduction of nitrogen oxides| US6667018B2|1994-07-05|2003-12-23|Ngk Insulators, Ltd.|Catalyst-adsorbent for purification of exhaust gases and method for purification of exhaust gases| US5589147A|1994-07-07|1996-12-31|Mobil Oil Corporation|Catalytic system for the reducton of nitrogen oxides| US5772972A|1995-01-09|1998-06-30|Ford Global Technologies, Inc.|Catalyst/hydrocarbon trap hybrid system| EP0756891A1|1995-07-26|1997-02-05|Corning Incorporated|Iron zeolite for conversion of NOx| DE19614540A1|1996-04-12|1997-10-16|Degussa|Diesel catalyst| JPH09276703A|1996-04-19|1997-10-28|Honda Motor Co Ltd|Catalyst for clening of exhaust gas| US5897846A|1997-01-27|1999-04-27|Asec Manufacturing|Catalytic converter having a catalyst with noble metal on molecular sieve crystal surface and method of treating diesel engine exhaust gas with same| DE19714536A1|1997-04-09|1998-10-15|Degussa|Car exhaust catalytic converter| CN1179357A|1997-08-18|1998-04-22|秦建武|Composite metal oxide catalyst and its preparing process| DE19753738A1|1997-12-04|1999-06-10|Degussa|Process for producing a catalyst| GB9805815D0|1998-03-19|1998-05-13|Johnson Matthey Plc|Manufacturing process| US6110862A|1998-05-07|2000-08-29|Engelhard Corporation|Catalytic material having improved conversion performance| AT236706T|1998-05-29|2003-04-15|Siemens Ag|METHOD FOR PURIFYING DIESEL ENGINE EXHAUST GAS| JP4012320B2|1998-10-15|2007-11-21|株式会社アイシーティー|Exhaust gas purification catalyst for lean combustion engine| JP2002530175A|1998-11-20|2002-09-17|コーニンクレッカフィリップスエレクトロニクスエヌヴィ|Catalyst-carrying filter| JP2000176298A|1998-12-11|2000-06-27|Mazda Motor Corp|Exhaust gas purification catalyst and its production| GB9919013D0|1999-08-13|1999-10-13|Johnson Matthey Plc|Reactor| WO2001047634A1|1999-12-28|2001-07-05|Corning Incorporated|Zeolite/alumina catalyst support compositions and method of making the same| EP1242182B1|1999-12-29|2005-11-02|Corning Incorporated|High strength and high surface area catalyst, catalyst support or adsorber compositions| US6569392B1|2000-02-02|2003-05-27|Ford Global Technologies Llc|Three-way rare earth oxide catalyst| ES2250035T3|2000-03-01|2006-04-16|UMICORE AG & CO. KG|CATALYST FOR PURIFICATION OF DIESEL ENGINE EXHAUST GASES AND PROCESS FOR PREPARATION.| US6602479B2|2000-06-27|2003-08-05|Ict Co., Ltd.|Exhaust gas purifying catalyst| JP4573320B2|2000-09-08|2010-11-04|昭和電工株式会社|Nitrous oxide decomposition catalyst, production method thereof, and decomposition method of nitrous oxide| DE10063220A1|2000-12-19|2002-06-20|Basf Ag|NOx storage catalyst, process for its production and its use| RU2199389C1|2001-09-17|2003-02-27|Институт катализа им. Г.К. Борескова СО РАН|Catalyst, catalyst support, method of preparation thereof , and method for removing nitrogen oxides from emission gases| JP3936238B2|2002-05-20|2007-06-27|株式会社デンソー|Catalyst body and method for producing catalyst body| JP2004060494A|2002-07-26|2004-02-26|Toyota Motor Corp|Exhaust emission control device of internal combustion engine| JP4228623B2|2002-08-23|2009-02-25|トヨタ自動車株式会社|Diesel exhaust gas purification equipment| PL1493484T3|2003-07-02|2007-05-31|Topsoe Haldor As|Process and filter for the catalytic treatment of diesel exhaust gas| US7229597B2|2003-08-05|2007-06-12|Basfd Catalysts Llc|Catalyzed SCR filter and emission treatment system| DE10340653B4|2003-09-03|2006-04-27|Hte Ag The High Throughput Experimentation Company|Catalyst for the removal of pollutants from exhaust gases of lean-burn engines with ruthenium as active metal| DE102004005997A1|2004-02-06|2005-09-01|Hte Ag The High Throughput Experimentation Company|Iron oxide stabilized noble metal catalyst for the removal of pollutants from exhaust gases from lean-burn engines| EP1748834A1|2004-04-16|2007-02-07|HTE Aktiengesellschaft The High Throughput Experimentation Company|Process for the removal of harmful substances from exhaust gases of combustion engines and catalyst for carrying out said process| WO2006068256A1|2004-12-22|2006-06-29|Hitachi Metals, Ltd.|Method for manufacturing honeycomb filter and honeycomb filter| US20060179825A1|2005-02-16|2006-08-17|Eaton Corporation|Integrated NOx and PM reduction devices for the treatment of emissions from internal combustion engines| MX2007010465A|2005-02-28|2008-01-14|Catalytic Solutions Inc|Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols.| DE102005024108A1|2005-05-25|2006-11-30|Süd-Chemie AG|Process and apparatus for the preparation of catalysts and their use in the purification of exhaust gases| WO2007000826A1|2005-06-27|2007-01-04|Ibiden Co., Ltd.|Honeycomb structure body| US7389638B2|2005-07-12|2008-06-24|Exxonmobil Research And Engineering Company|Sulfur oxide/nitrogen oxide trap system and method for the protection of nitrogen oxide storage reduction catalyst from sulfur poisoning| JP2007196146A|2006-01-27|2007-08-09|Babcock Hitachi Kk|Catalyst for cleaning exhaust gas| US7829062B2|2006-02-14|2010-11-09|Exxonmobil Chemical Patent Inc.|Method of preparing a molecular sieve composition| JP2007296514A|2006-04-07|2007-11-15|Ngk Insulators Ltd|Catalytic body and manufacturing method of the same| DE102006020158B4|2006-05-02|2009-04-09|Argillon Gmbh|Extruded full catalyst and process for its preparation| FR2905371B1|2006-08-31|2010-11-05|Rhodia Recherches & Tech|HIGH REDUCIBILITY COMPOSITION BASED ON NANOMETRY CERIUM OXIDE ON A CARRIER, PREPARATION METHOD AND USE AS CATALYST| US7759280B2|2006-09-20|2010-07-20|Basf Corporation|Catalysts, systems and methods to reduce NOX in an exhaust gas stream| CN101528326B|2006-10-23|2012-08-29|尤米科尔股份公司及两合公司|Vanadium-free catalyst for selective catalytic reduction and process for its preparation| CN100998941B|2007-01-04|2012-09-05|华东理工大学|Precatalyst and its preparation method| US7645718B2|2007-03-26|2010-01-12|Pq Corporation|Microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same| EP3300791B1|2007-04-26|2019-03-27|Johnson Matthey Public Limited Company|Transition metal/zeolite scr catalysts| CN101322941A|2007-06-13|2008-12-17|曾庆琳|Energy-saving type nano-catalyst for purifying vehicle tail gas| WO2008154739A1|2007-06-18|2008-12-24|Valorbec Societe En Commandite|Co-catalysts for hybrid catalysts, hybrid catalysts comprising same, monocomponent catalysts, methods of manufacture and uses thereof| GB2450484A|2007-06-25|2008-12-31|Johnson Matthey Plc|Non-Zeolite base metal catalyst| CN201050105Y|2007-06-26|2008-04-23|郭太成|Automatic toilet seat| KR101513887B1|2007-07-26|2015-04-21|삼성전자주식회사|Method and apparatus for discovering location of information server and method and apparatus for receiving handover information using the location of information server| WO2009073099A1|2007-11-30|2009-06-11|Corning Incorporated|Zeolite-based honeycomb body| DE102007061776A1|2007-12-20|2009-06-25|Argillon Gmbh|Process for drying ceramic honeycomb bodies| GB2457651A|2008-01-23|2009-08-26|Johnson Matthey Plc|Catalysed wall-flow filter| US7695703B2|2008-02-01|2010-04-13|Siemens Energy, Inc.|High temperature catalyst and process for selective catalytic reduction of NOx in exhaust gases of fossil fuel combustion| JP2009255034A|2008-03-27|2009-11-05|Ibiden Co Ltd|Honeycomb structure and apparatus of treating exhaust gas| JPWO2009118868A1|2008-03-27|2011-07-21|イビデン株式会社|Honeycomb structure| JP2009255030A|2008-03-27|2009-11-05|Ibiden Co Ltd|Honeycomb structure| WO2009141889A1|2008-05-20|2009-11-26|イビデン株式会社|Honeycomb structure| JPWO2009141895A1|2008-05-20|2011-09-22|イビデン株式会社|Exhaust gas purification device| CN101678351B|2008-05-20|2012-07-04|揖斐电株式会社|Honeycomb structure| JP5356065B2|2008-05-20|2013-12-04|イビデン株式会社|Honeycomb structure| JP2010000499A|2008-05-20|2010-01-07|Ibiden Co Ltd|Honeycomb structure| WO2009141884A1|2008-05-20|2009-11-26|イビデン株式会社|Honeycomb structure| KR100997579B1|2008-07-08|2010-11-30|임재주|Lifesaving rope| US20100050604A1|2008-08-28|2010-03-04|John William Hoard|SCR-LNT CATALYST COMBINATION FOR IMPROVED NOx CONTROL OF LEAN GASOLINE AND DIESEL ENGINES| CN101485980B|2009-02-27|2012-09-05|中国科学院大连化学物理研究所|Catalyst structure composed of zeolite and redox oxide| US8703636B2|2009-02-27|2014-04-22|Corning Incorporated|Method of manufacturing a catalyst body by post-impregnation| GB2482094B|2009-04-17|2014-05-14|Johnson Matthey Plc|Small pore molecular sieve supported copper catalysts durable against lean/rich ageing for the reduction of nitrogen oxides| US20100296992A1|2009-05-22|2010-11-25|Yi Jiang|Honeycomb Catalyst And Catalytic Reduction Method| DE102009040352A1|2009-09-05|2011-03-17|Johnson Matthey Catalysts Gmbh|Process for the preparation of an SCR active zeolite catalyst and SCR active zeolite catalyst| US8557203B2|2009-11-03|2013-10-15|Umicore Ag & Co. Kg|Architectural diesel oxidation catalyst for enhanced NO2 generator| GB201000019D0|2010-01-04|2010-02-17|Johnson Matthey Plc|Coating a monolith substrate with catalyst component| EP2531280B1|2010-02-01|2014-12-24|Johnson Matthey Public Limited Company|NOx ABSORBER CATALYSTS| US8529853B2|2010-03-26|2013-09-10|Umicore Ag & Co. Kg|ZrOx, Ce-ZrOx, Ce-Zr-REOx as host matrices for redox active cations for low temperature, hydrothermally durable and poison resistant SCR catalysts|US5622786A|1994-11-30|1997-04-22|Kimberly-Clark Corporation|Polymer-reinforced, eucalyptus fiber-containing paper| WO2008143792A1|2007-05-11|2008-11-27|Sdc Materials, Inc.|Formation of catalytic regions within porous structures using supercritical phase processing| US8507401B1|2007-10-15|2013-08-13|SDCmaterials, Inc.|Method and system for forming plug and play metal catalysts| US9149797B2|2009-12-15|2015-10-06|SDCmaterials, Inc.|Catalyst production method and system| US8652992B2|2009-12-15|2014-02-18|SDCmaterials, Inc.|Pinning and affixing nano-active material| US8803025B2|2009-12-15|2014-08-12|SDCmaterials, Inc.|Non-plugging D.C. plasma gun| US8557727B2|2009-12-15|2013-10-15|SDCmaterials, Inc.|Method of forming a catalyst with inhibited mobility of nano-active material| US9090475B1|2009-12-15|2015-07-28|SDCmaterials, Inc.|In situ oxide removal, dispersal and drying for silicon SiO2| US9126191B2|2009-12-15|2015-09-08|SDCmaterials, Inc.|Advanced catalysts for automotive applications| EP2531280B1|2010-02-01|2014-12-24|Johnson Matthey Public Limited Company|NOx ABSORBER CATALYSTS| CA2755977C|2010-03-15|2014-01-21|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| KR101383422B1|2010-03-15|2014-04-08|도요타지도샤가부시키가이샤|Exhaust purification system of internal combustion engine| US9032711B2|2010-04-01|2015-05-19|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| JP5937579B2|2010-06-10|2016-06-22|ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ|NOx storage catalyst with improved hydrocarbon conversion activity| FR2962923B1|2010-07-22|2015-01-02|Peugeot Citroen Automobiles Sa|CATALYTIC COMPOSITION AND DEVICE FOR TREATING GASES COMPRISING SUCH A COMPOSITION| DE102010032576A1|2010-07-28|2012-02-02|Emitec Gesellschaft Für Emissionstechnologie Mbh|Device for near-exhaust gas treatment| CN102985647B|2010-07-28|2015-06-03|丰田自动车株式会社|Exhaust purification apparatus for internal combustion engine| ES2554637T3|2010-08-30|2015-12-22|Toyota Jidosha Kabushiki Kaisha|Exhaust gas purification device for internal combustion engine| JP5067511B2|2010-08-30|2012-11-07|トヨタ自動車株式会社|Exhaust gas purification device for internal combustion engine| ES2600959T3|2010-09-02|2017-02-13|Toyota Jidosha Kabushiki Kaisha|NOx purification method of an exhaust gas purification system of an internal combustion engine| EP3103979B1|2010-09-13|2018-01-03|Umicore AG & Co. KG|Catalytic convertor for removing nitrogen oxides from the exhaust gas of diesel engines| WO2012046333A1|2010-10-04|2012-04-12|トヨタ自動車株式会社|Exhaust gas purifying device for internal combustion engine| ES2584605T3|2010-10-04|2016-09-28|Toyota Jidosha Kabushiki Kaisha|Exhaust gas purification method in internal combustion engine exhaust gas purification system| CN103154459B|2010-10-18|2015-07-15|丰田自动车株式会社|Exhaust gas purification device for internal combustion engine| JP5168411B2|2010-12-06|2013-03-21|トヨタ自動車株式会社|Exhaust gas purification device for internal combustion engine| US9108154B2|2010-12-20|2015-08-18|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| GB201021887D0|2010-12-21|2011-02-02|Johnson Matthey Plc|Oxidation catalyst for a lean burn internal combustion engine| BRPI1014480A2|2010-12-24|2021-06-29|Toyota Jidosha Kabushiki Kaisha|internal combustion engine exhaust purification system| CN102753794B|2011-02-07|2015-05-13|丰田自动车株式会社|Exhaust-gas purifying device for internal-combustion engine| US9140162B2|2011-02-10|2015-09-22|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| US8669202B2|2011-02-23|2014-03-11|SDCmaterials, Inc.|Wet chemical and plasma methods of forming stable PtPd catalysts| WO2012124173A1|2011-03-17|2012-09-20|トヨタ自動車株式会社|Internal combustion engine exhaust gas purification device| CN102834595B|2011-04-15|2015-08-05|丰田自动车株式会社|The Exhaust gas purifying device of internal-combustion engine| US8763364B2|2011-04-18|2014-07-01|Chevron U.S.A. Inc.|Treatment of cold start engine exhaust| GB2504024B|2011-08-03|2014-03-12|Johnson Matthey Plc|Extruded honeycomb catalyst| WO2013024548A1|2011-08-18|2013-02-21|イビデン株式会社|Honeycomb structure, manufacturing method therefor, exhaust gas purification device, and silicoaluminophosphate particles| EP2745935A4|2011-08-18|2015-05-27|Ibiden Co Ltd|Honeycomb structure, method for producing same, exhaust gas purification device, and silicoaluminophosphate particles| CN103945919A|2011-08-19|2014-07-23|Sdc材料公司|Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions| WO2013047908A1|2011-09-29|2013-04-04|日本碍子株式会社|Honeycomb filter and production method for same| CN103958033B|2011-09-30|2016-06-15|皮雷利&C.环境有限责任公司|Exhausted gas post-processing system, Catalysts and its preparation method for described system| JP5938819B2|2011-10-06|2016-06-22|ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ|Oxidation catalyst for exhaust gas treatment| US9034268B2|2011-11-07|2015-05-19|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| EP2626529B1|2011-11-09|2015-10-21|Toyota Jidosha Kabushiki Kaisha|Exhaust purification device for internal combustion engine| US9175590B2|2011-11-30|2015-11-03|Toyota Jidosha Kabushiki Kaisha|Exhaust purification system of internal combustion engine| WO2013080330A1|2011-11-30|2013-06-06|トヨタ自動車株式会社|Exhaust purification device for internal combustion engine| GB2497597A|2011-12-12|2013-06-19|Johnson Matthey Plc|A Catalysed Substrate Monolith with Two Wash-Coats| GB201200784D0|2011-12-12|2012-02-29|Johnson Matthey Plc|Exhaust system for a lean-burn internal combustion engine including SCR catalyst| GB201200781D0|2011-12-12|2012-02-29|Johnson Matthey Plc|Exhaust system for a lean-burn ic engine comprising a pgm component and a scr catalyst| GB201200783D0|2011-12-12|2012-02-29|Johnson Matthey Plc|Substrate monolith comprising SCR catalyst| WO2013096069A2|2011-12-22|2013-06-27|Uop Llc|Uzm-39 aluminosilicate zeolite| JP2015515429A|2011-12-22|2015-05-28|ユーオーピー エルエルシー|Layered conversion synthesis of zeolite.| WO2013096075A2|2011-12-22|2013-06-27|Uop Llc|Aromatic transformation using uzm-39 aluminosilicate zeolite| JP5635488B2|2011-12-28|2014-12-03|本田技研工業株式会社|Exhaust purification catalyst| EP2642096B1|2012-01-30|2016-10-05|Toyota Jidosha Kabushiki Kaisha|Exhaust purification device of internal combustion engine| JP5392411B1|2012-02-07|2014-01-22|トヨタ自動車株式会社|Exhaust gas purification device for internal combustion engine| CN104144746A|2012-03-02|2014-11-12|巴斯夫欧洲公司|Porous inorganic body| JP5926593B2|2012-03-28|2016-05-25|日本碍子株式会社|Porous material, method for producing the same, and honeycomb structure| US8765085B2|2012-04-26|2014-07-01|Basf Corporation|Base metal catalyst and method of using same| US8668890B2|2012-04-26|2014-03-11|Basf Corporation|Base metal catalyst composition and methods of treating exhaust from a motorcycle| KR101535088B1|2012-06-12|2015-07-08|희성촉매 주식회사|SCR catalyst system with high performance| US20140044625A1|2012-08-08|2014-02-13|Ford Global Technologies, Llc|Hydrocarbon trap having improved adsorption capacity| US8568674B1|2012-08-10|2013-10-29|Basf Corporation|Diesel oxidation catalyst composites| WO2014038690A1|2012-09-10|2014-03-13|東ソー株式会社|Silicoaluminophosphate salt and nitrogen oxide reduction catalyst including same| US9156025B2|2012-11-21|2015-10-13|SDCmaterials, Inc.|Three-way catalytic converter using nanoparticles| US9511352B2|2012-11-21|2016-12-06|SDCmaterials, Inc.|Three-way catalytic converter using nanoparticles| WO2014093440A1|2012-12-12|2014-06-19|Uop Llc|Conversion of methane to aromatic compounds using uzm-44 aluminosilicate zeolite| US8623321B1|2012-12-12|2014-01-07|Uop Llc|UZM-44 aluminosilicate zeolite| US8609911B1|2012-12-12|2013-12-17|Uop Llc|Catalytic pyrolysis using UZM-44 aluminosilicate zeolite| US20140163281A1|2012-12-12|2014-06-12|Uop Llc|Conversion of methane to aromatic compounds using a catalytic composite| US8889939B2|2012-12-12|2014-11-18|Uop Llc|Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite| US8609910B1|2012-12-12|2013-12-17|Uop Llc|Catalytic pyrolysis using UZM-39 aluminosilicate zeolite| US8618343B1|2012-12-12|2013-12-31|Uop Llc|Aromatic transalkylation using UZM-39 aluminosilicate zeolite| US8609921B1|2012-12-12|2013-12-17|Uop Llc|Aromatic transalkylation using UZM-44 aluminosilicate zeolite| US8609919B1|2012-12-12|2013-12-17|Uop Llc|Aromatic transformation using UZM-44 aluminosilicate zeolite| US8912378B2|2012-12-12|2014-12-16|Uop Llc|Dehydrocyclodimerization using UZM-39 aluminosilicate zeolite| KR101438953B1|2012-12-18|2014-09-11|현대자동차주식회사|LNT Catalysts with Enhanced Storage Capacities of Nitrogen Oxide at Low Temperature| US9266092B2|2013-01-24|2016-02-23|Basf Corporation|Automotive catalyst composites having a two-metal layer| CN105188931A|2013-03-14|2015-12-23|巴斯夫公司|Catalytic article with segregated washcoat and methods of making same| CN104043330B|2013-03-15|2017-03-01|通用电气公司|The method of oxidation carbonaceous material, diesel particulate trap and exhaust apparatus| EP2980050B1|2013-03-29|2019-10-23|NGK Insulators, Ltd.|Aluminophosphate-metal oxide bonded body and production method for same| CN103406139A|2013-06-04|2013-11-27|东南大学|Preparation method of molecular sieve integral type catalyst with high mechanical stability| EP3024571B1|2013-07-25|2020-05-27|Umicore AG & Co. KG|Washcoats and coated substrates for catalytic converters| CN106061605A|2013-07-31|2016-10-26|研究三角协会|Mixed metal iron oxides and uses thereof| JP5922629B2|2013-09-27|2016-05-24|日本碍子株式会社|Porous material, method for producing the same, and honeycomb structure| MX2016004759A|2013-10-22|2016-07-26|Sdcmaterials Inc|Compositions of lean nox trap.| KR20160074566A|2013-10-22|2016-06-28|에스디씨머티리얼스, 인코포레이티드|Catalyst design for heavy-duty diesel combustion engines| JP6208540B2|2013-10-29|2017-10-04|トヨタ自動車株式会社|Exhaust gas purification catalyst| EP3062926A1|2013-10-30|2016-09-07|Johnson Matthey Public Limited Company|Three-way catalyst comprising a silver-containing extruded zeolite substrate and its use in exhaust systems| CN105722591B|2013-12-04|2018-09-11|三井金属矿业株式会社|Exhaust gas purification catalyst and exhaust gas purification catalyst constitute body| EP3077084B1|2013-12-06|2019-02-06|Johnson Matthey Public Limited Company|Cold start catalyst and its use in exhaust systems| US10864502B2|2013-12-16|2020-12-15|Basf Corporation|Manganese-containing diesel oxidation catalyst| US10335776B2|2013-12-16|2019-07-02|Basf Corporation|Manganese-containing diesel oxidation catalyst| RU2544241C1|2014-01-22|2015-03-20|Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез"|Method of producing aromatic hydrocarbons from natural gas and apparatus therefor| GB201401115D0|2014-01-23|2014-03-12|Johnson Matthey Plc|Diesel oxidation catalyst and exhaust system| DE102014201263A1|2014-01-23|2015-07-23|Johnson Matthey CatalystsGmbh|catalyst| RU2544017C1|2014-01-28|2015-03-10|Ольга Васильевна Малова|Catalyst and method for aromatisation of c3-c4 gases, light hydrocarbon fractions of aliphatic alcohols, as well as mixtures thereof| WO2015126025A1|2014-02-18|2015-08-27|한국생산기술연구원|Scr catalyst comprising vanadium and tungsten supported on carbon material and method for preparing same| EP3119500A4|2014-03-21|2017-12-13|SDC Materials, Inc.|Compositions for passive nox adsorptionsystems| DE102014205760A1|2014-03-27|2015-10-01|Johnson Matthey Public Limited Company|Process for producing a catalyst and catalyst| DE102014205783A1|2014-03-27|2015-10-01|Johnson Matthey Public Limited Company|Catalyst and method for producing a catalyst| RU2550354C1|2014-03-28|2015-05-10|Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез"|Method for producing aromatic hydrocarbon concentrate of light aliphatic hydrocarbons and device for implementing it| RU2671574C2|2014-04-10|2018-11-02|Мицубиси Газ Кемикал Компани, Инк.|Molded catalyst for use in the manufacture of methyl methacrylate and method for manufacture of methyl methacrylate using the specified catalyst| KR101575327B1|2014-04-24|2015-12-21|현대자동차 주식회사|Catalyst for abating nitrogen oxide, method for preparing the same, and catalyst system for abating nitrogen oxide| RU2561638C1|2014-05-21|2015-08-27|Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Дальневосточный государственный технический рыбохозяйственный университет" |Method of manufacturing of formed ceramic membranes| US9267409B2|2014-06-18|2016-02-23|Ford Global Technologies, Llc|Reverse flow hydrocarbon trap| DE102014215112A1|2014-07-31|2016-02-04|Johnson Matthey Public Limited Company|Process for preparing a catalyst and catalyst articles| JP6248011B2|2014-08-08|2017-12-13|株式会社デンソー|Honeycomb structure and manufacturing method thereof| RU2558955C1|2014-08-12|2015-08-10|Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез"|Method of producing aromatic hydrocarbon concentrate from liquid hydrocarbon fractions and apparatus therefor| CN112983615A|2014-12-31|2021-06-18|康明斯排放处理公司|Single-module integrated post-processing module| GB2547873B|2014-12-31|2021-03-10|Cummins Emission Solutions Inc|Close coupled single module aftertreatment system| CN110206625A|2014-12-31|2019-09-06|康明斯排放处理公司|Compact side formula entrance exhaust after treatment system| JP2016131918A|2015-01-19|2016-07-25|大塚化学株式会社|Method for producing exhaust gas purification filter, exhaust gas purification filter, and exhaust gas purification device| US20160207840A1|2015-01-21|2016-07-21|The Boeing Company|Extrudable ceramic composition and method of making| EP3253488A1|2015-02-06|2017-12-13|Johnson Matthey Public Limited Company|Three-way catalyst and its use in exhaust systems| GB201504986D0|2015-02-13|2015-05-06|Johnson Matthey Plc|Oxidation catalyst for treating a natural gas emission| CN106031861A|2015-03-19|2016-10-19|上海融熠投资管理有限公司|Composite adsorbent| CN104826395A|2015-04-21|2015-08-12|蚌埠德美过滤技术有限公司|Antistatic adsorption filtering agent and preparation method thereof| CN104826385A|2015-04-29|2015-08-12|安徽天诚环保机械有限公司|Novel environment-friendly modified active carbon filter material and preparation method thereof| JP6787935B2|2015-06-18|2020-11-18|ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ|Single-layer or double-layer ammonia slip catalyst| MX2018000142A|2015-06-29|2018-02-19|Corning Inc|Porous ceramic body to reduce emissions.| US10267199B2|2015-07-28|2019-04-23|Cummins Emission Solutions Inc.|Angled sensor mount for use with a single module aftertreatment system or the like| GB2556753B|2015-08-03|2020-12-09|Cummins Emission Solutions Inc|Sensor configuration for aftertreatment system including SCR on filter| KR102360435B1|2015-09-21|2022-02-09|한국전력공사|Apparatus for exhaust gas purification and exhaust gas purification method| USD794100S1|2015-09-28|2017-08-08|Cummins Emission Solutions Inc.|Aftertreatment system housing| CN108136385A|2015-09-30|2018-06-08|佛兰芒技术研究所有限公司|Catalyst composition and the structure being made from it| CN106608637B|2015-10-27|2019-02-01|中国石油化工股份有限公司|A method of synthesis STT structure molecular screen| CN105214706B|2015-10-28|2018-07-31|杭州正清环保科技有限公司|A kind of catalytic ceramics sintered ring and preparation method for exhaust-gas treatment| US10188986B2|2015-11-06|2019-01-29|Paccar Inc|Electrochemical reductant generation while dosing DEF| US9764287B2|2015-11-06|2017-09-19|Paccar Inc|Binary catalyst based selective catalytic reduction filter| US9757691B2|2015-11-06|2017-09-12|Paccar Inc|High efficiency and durability selective catalytic reduction catalyst| US10058819B2|2015-11-06|2018-08-28|Paccar Inc|Thermally integrated compact aftertreatment system| GB2545747A|2015-12-24|2017-06-28|Johnson Matthey Plc|Gasoline particulate filter| JP6578938B2|2015-12-25|2019-09-25|株式会社デンソー|Exhaust gas filter| EP3205398A1|2016-02-12|2017-08-16|Hyundai Motor Company|Method for preparing zeolite catalyst| CN107042122A|2016-04-11|2017-08-15|北京为康环保科技有限公司|A kind of photocatalysis causes the preparation method of haze gas purification spray| CN109153627A|2016-04-21|2019-01-04|罗门哈斯公司|The method of macropore inert material is used in monomer production| CN105797708B|2016-04-27|2018-02-16|柳州申通汽车科技有限公司|A kind of preparation technology of ternary tail-gas catalyst| CN105772025B|2016-04-27|2018-03-16|柳州申通汽车科技有限公司|The preparation method of ternary catalyst for automobile tail gas| CN105903467B|2016-04-27|2018-03-16|柳州申通汽车科技有限公司|The preparation method of Pd-only automobile exhaust catalyst| CN105797745A|2016-04-27|2016-07-27|柳州申通汽车科技有限公司|Method for preparing automobile exhaust ternary catalyst by impregnation method| CN105797744B|2016-04-27|2018-02-27|柳州申通汽车科技有限公司|A kind of preparation technology of ternary catalyst for automobile tail gas| CN105817230B|2016-04-27|2018-04-24|柳州申通汽车科技有限公司|The preparation method of ternary tail-gas catalyst| CN105797737B|2016-04-27|2018-04-24|柳州申通汽车科技有限公司|A kind of preparation method of three-way catalyst| CN105688933B|2016-04-27|2018-03-20|柳州申通汽车科技有限公司|The technique that ball-milling method prepares three-way catalyst| CN105688905B|2016-04-27|2018-03-16|柳州申通汽车科技有限公司|The preparation technology of auto-exhaust catalyst| CN105772026B|2016-04-27|2018-04-24|柳州申通汽车科技有限公司|A kind of preparation method of auto-exhaust catalyst| BR112018072074A2|2016-04-29|2019-02-12|Johnson Matthey Public Limited Company|exhaust system for an internal combustion engine, catalytic wall flow monolithic substrate, methods for making a catalyzed monolithic substrate and for treating exhaust gases from an internal combustion engine, compression ignition engine, and vehicle.| US10253669B2|2016-05-12|2019-04-09|CDT Advanced Materials, Inc.|Application of synergized-PGM with ultra-low PGM loadings as underfloor three-way catalysts for internal combustion engines| US10533472B2|2016-05-12|2020-01-14|Cdti Advanced Materials, Inc.|Application of synergized-PGM with ultra-low PGM loadings as close-coupled three-way catalysts for internal combustion engines| KR101795404B1|2016-05-18|2017-11-08|현대자동차 주식회사|Catalyst and manufacturing method of catalyst| GB2552262B|2016-07-12|2021-02-10|Johnson Matthey Plc|Oxidation catalyst for a stoichiometric natural gas engine| JP6998871B2|2016-07-14|2022-01-18|イビデン株式会社|Honeycomb structure and method for manufacturing the honeycomb structure| CN106238031A|2016-07-26|2016-12-21|浙江三龙催化剂有限公司|Cerium oxide base SCR catalyst for denitrating flue gas| CN106238032A|2016-07-26|2016-12-21|浙江三龙催化剂有限公司|The manufacture method of cerium oxide base SCR catalyst for denitrating flue gas| CN106345515B|2016-07-31|2018-07-06|合肥学院|A kind of preparation method of Ce-Zn-Co-Cu mixing and dopings ZSM-5 zeolite molecular sieve| GB201616812D0|2016-10-04|2016-11-16|Johnson Matthey Public Limited Company|NOx adsorber catalyst| GB2560130B|2016-10-21|2021-10-20|Cummins Emission Solutions Inc|Catalyst substrate and filter structure including plates and method of forming same| CA3041422A1|2016-10-24|2018-05-03|Basf Corporation|Integrated scr catalyst and lnt for nox abatement| GB2571039A|2016-10-31|2019-08-14|Johnson Matthey Plc|LTA catalysts having extra-framework iron and/or manganese for treating exhaust gas| CN107051466B|2016-12-30|2019-06-18|浙江大学|Boat diesel engine SCR denitration of efficient removal soot and preparation method thereof| MX2019009466A|2017-02-08|2019-11-28|Basf Corp|Catalytic articles.| WO2018146602A1|2017-02-08|2018-08-16|Basf Corporation|Catalyst compositions| EP3363540B1|2017-02-17|2019-07-24|Umicore Ag & Co. Kg|Copper containing moz zeolite for selective nox reduction catalysis| JP2018143955A|2017-03-06|2018-09-20|イビデン株式会社|Honeycomb filter| JP2018143956A|2017-03-06|2018-09-20|イビデン株式会社|Honeycomb filter| GB2560940A|2017-03-29|2018-10-03|Johnson Matthey Plc|Three layer NOx Adsorber catalyst| GB2560942A|2017-03-29|2018-10-03|Johnson Matthey Plc|NOx Adsorber catalyst| GB2560941A|2017-03-29|2018-10-03|Johnson Matthey Plc|NOx Adsorber catalyst| GB201705158D0|2017-03-30|2017-05-17|Johnson Matthey Plc|Catalyst article for use in a emission treatment system| GB201705279D0|2017-03-31|2017-05-17|Johnson Matthey Plc|Selective catalytic reduction catalyst| GB201705289D0|2017-03-31|2017-05-17|Johnson Matthey CatalystsGmbh|Selective catalytic reduction catalyst| CN106984148A|2017-04-24|2017-07-28|河北工业大学|A kind of method of low-temperature plasma synergistic catalysis oxidation various pollutants in fume| JP6408062B1|2017-04-28|2018-10-17|株式会社キャタラー|Exhaust gas purification catalyst| CN108862294A|2017-05-08|2018-11-23|上海大学|A kind of nanometer of praseodymium zirconium yellow material and preparation method thereof| WO2018206531A1|2017-05-11|2018-11-15|Rhodia Operations|Mixed oxide with enhanced resistance and no x storage capacity| US10675586B2|2017-06-02|2020-06-09|Paccar Inc|Hybrid binary catalysts, methods and uses thereof| US10835866B2|2017-06-02|2020-11-17|Paccar Inc|4-way hybrid binary catalysts, methods and uses thereof| CN111491726A|2017-09-27|2020-08-04|庄信万丰股份有限公司|Low surface coating supported single layer catalyst for gasoline exhaust gas cleaning applications| JP2019084482A|2017-11-03|2019-06-06|株式会社デンソー|Exhaust gas purification device| US10220376B1|2017-12-05|2019-03-05|James G. Davidson|Catalytic composition and system for exhaust purification| RU2020116420A3|2017-12-08|2022-01-11| EP3721990A4|2017-12-08|2021-09-01|Johnson MattheyChemicals Limited|Novel multi-region twc for treatment of exhaust gas from gasoline engine| US10634078B2|2017-12-11|2020-04-28|Ford Global Technologies, Llc|Methods and systems for an exhaust aftertreatment device| GB201805312D0|2018-03-29|2018-05-16|Johnson Matthey Plc|Catalyst article for use in emission treatment system| CN108855207B|2018-06-17|2021-04-27|复旦大学|Heteroatom Beta zeolite catalyst containing alkali metal and preparation method and application thereof| CN108855132B|2018-06-26|2020-06-05|中国石油大学|Hierarchical pore cerium-zirconium oxide supported spinel type palladium-cobalt composite oxide catalyst| EP3844126A1|2018-08-31|2021-07-07|Corning Incorporated|Methods of making honeycomb bodies having inorganic filtration deposits| JP6764451B2|2018-09-12|2020-09-30|イビデン株式会社|Manufacturing method of honeycomb structure| KR102193496B1|2018-09-21|2020-12-21| 세라컴|Diesel oxidation catalyst with excellent heat durability and Method thereof| GB2579878A|2018-09-28|2020-07-08|Johnson Matthey Plc|Novel TWC catalysts for gasoline exhaust gas applications| CN109225317A|2018-10-29|2019-01-18|钟祥博谦信息科技有限公司|A kind of synthesis technology of the supported precious metal palladium on AFI aluminophosphate molecular sieve membrane| KR102150081B1|2018-11-19|2020-09-02|한국화학연구원|Zeolite-based scr catalyst, method for producing the same, and method for treating an exhaust gas using the same| GB201903006D0|2019-03-06|2019-04-17|Johnson Matthey Plc|Lean nox trap catalyst| US10906031B2|2019-04-05|2021-02-02|Paccar Inc|Intra-crystalline binary catalysts and uses thereof| US11007514B2|2019-04-05|2021-05-18|Paccar Inc|Ammonia facilitated cation loading of zeolite catalysts| EP3741449A1|2019-05-21|2020-11-25|Haldor Topsøe A/S|A process for the removal of dinitrogen oxide in process off-gas| CN110270341B|2019-06-19|2021-01-01|福州大学|Catalyst and preparation method and application thereof| KR20210034783A|2019-09-23|2021-03-31|희성촉매 주식회사|Low temperature NOx absorption composition and DOC containing the same| CN110639608A|2019-09-24|2020-01-03|中国科学院大连化学物理研究所|High-concentration ethylene liquid-phase alkylation catalyst for benzene absorption and preparation method and application thereof| WO2021058484A1|2019-09-27|2021-04-01|Johnson Matthey CatalystsGmbh|MULTI-FUNCTION CATALYST ARTICLE FOR TREATING BOTH CO AND NOx IN STATIONARY EMISSION SOURCE EXHAUST GAS| US10934918B1|2019-10-14|2021-03-02|Paccar Inc|Combined urea hydrolysis and selective catalytic reduction for emissions control| US20210113994A1|2019-10-18|2021-04-22|Carus Llc|MIXED VALENT MANGANESE-BASED NOx ADSORBER| GB201917634D0|2019-12-03|2020-01-15|Johnson Matthey Catalysts Germany Gmbh|Element frame assemblies containing monoliths|
法律状态:
2018-04-10| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]| 2019-10-01| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]| 2020-12-22| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]| 2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]| 2021-05-25| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 01/02/2011, OBSERVADAS AS CONDICOES LEGAIS. PATENTE CONCEDIDA CONFORME ADI 5.529/DF |
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 US30027910P| true| 2010-02-01|2010-02-01| US61/300,279|2010-02-01| PCT/GB2011/050160|WO2011092519A1|2010-02-01|2011-02-01|Oxidation catalyst| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|